Title of article
New class of β-aminoalcohol ligands derived from isosorbide and isomannide: application in hydrogen transfer reduction of prochiral ketones
Author/Authors
Tin Thanh Le، نويسنده , , Stéphane Guillarme، نويسنده , , Christine Saluzzo، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
6
From page
8893
To page
8898
Abstract
Starting from isosorbide and isomannide, two by-products from the starch industry, a family of chiral functionalized β-aminoalcohols presenting a THF ring has been synthesized as potential ligands for hydrogen transfer reduction of prochiral ketones. Under optimal conditions, more than 70% ee with an excellent conversion were obtained for the HTR of the acetophenone.
Keywords
biomass , ?-Aminoalcohols , Homogeneous catalysis , enantioselective catalysis , Asymmetric hydrogen transfer reduction
Journal title
Tetrahedron
Serial Year
2010
Journal title
Tetrahedron
Record number
1102654
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