• Title of article

    Synthesis of α-silylcarboxylic acids

  • Author/Authors

    Alex V. Shtelman، نويسنده , , James Y. Becker، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2011
  • Pages
    7
  • From page
    1135
  • To page
    1141
  • Abstract
    New α-silylacetic acids have been prepared following a general and convenient procedure of a one-pot reaction between trimethylsilylacetate and different chlorosilanes. New derivatives of diphenyl(methyl)silylacetic acid were prepared by a direct alkylation of its dianion with benzyl-, allyl-, and alkyl halides and trimethylchlorogermane to afford new α-silylcarboxylic acids.
  • Keywords
    ?-Silylcarboxylic acids , Alkylation , ? , Chlorosilanes , ??-Disilyldicarboxylic acids , ?-Silylacetic acid dianion
  • Journal title
    Tetrahedron
  • Serial Year
    2011
  • Journal title
    Tetrahedron
  • Record number

    1102929