Title of article
Axially chiral phosphine–oxazoline ligands in silver(I)-catalyzed asymmetric Mannich reaction of N-Boc aldimines with trimethylsiloxyfuran
Author/Authors
Qian-Yi Zhao، نويسنده , , Min Shi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
9
From page
3724
To page
3732
Abstract
Axially chiral phosphine–oxazoline ligand L6 was found to be a fairly effective chiral ligand in silver(I)-catalyzed asymmetric Mannich reaction of N-Boc aldimines with trimethylsiloxyfuran to give the corresponding adducts in up to 97% yield, 7:1 dr and 86% ee (major diastereoisomer).
Keywords
Trimethylsiloxyfuran , Silver acetate , Asymmetric Mannich reaction , N-Boc aldimines , Axially chiral phosphine–oxazoline ligands
Journal title
Tetrahedron
Serial Year
2011
Journal title
Tetrahedron
Record number
1103233
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