Title of article
Synthesis of new serine-based phosphinooxazoline ligands and iridium complexes for asymmetric hydrogenations
Author/Authors
Axel Franzke، نويسنده , , Felix Voss، نويسنده , , Andreas Pfaltz، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
6
From page
4358
To page
4363
Abstract
A series of serine-based phosphinooxazoline ligands was synthesized and the corresponding iridum complexes were successfully applied in the asymmetric hydrogenation of various unfunctionalized olefines and acetophenone-N-phenyl-imine. The results show that these new derivatives are useful substitutes for the standard tert-leucine-derived PHOX ligands.
Keywords
Hydrogenation , p , N-ligands , Iridium , Asymmetric catalysis
Journal title
Tetrahedron
Serial Year
2011
Journal title
Tetrahedron
Record number
1103310
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