Title of article :
Silicomolybdic acid supported on silica gel: an efficient catalyst for Hosomi–Sakurai reactions
Author/Authors :
Kaliyappan Murugan، نويسنده , , Sankareswaran Srimurugan، نويسنده , , Chinpiao Chen، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2011
Abstract :
Silicomolybdic acid that is supported on silica gel (50 wt %) efficiently catalyzes the high-yielding Hosomi–Sakurai allylation of carbonyl compounds by allyltrimethylsilane in the presence of benzyl alcohol. The reaction rates of inactive substrates and the yields were greatly increased when preformed acetals were used as substrates.
Keywords :
Silicomolybdic acid (SMA) , Hosomi–Sakurai reaction , Br?nsted acids , Allylation , Homoallylic ether
Journal title :
Tetrahedron
Journal title :
Tetrahedron