Title of article
Concise stereoselective synthesis of marine sesterterpene, 16-deacetoxy-12-epi-scalarafuran acetate and its 14-epimer via intramolecular Diels–Alder addition
Author/Authors
Zheng-Lin Wang، نويسنده , , Zi-Gang Zhang، نويسنده , , Hong-Chang Li، نويسنده , , Wei-Ping Deng، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
5
From page
6939
To page
6943
Abstract
The stereoselective synthesis of C12 oxygenated marine scalaranic sesterterpene 16-deacetoxy-12-epi-scalarafuran acetate and its 14-epimer were described. A highly stereoselective intramolecular Diels–Alder addition was designed as the key step to construct the ring D, and the absolute configurations of natural 16-deacetoxy-12-epi-scalarafuran acetate was supported by the X-ray diffraction analysis of single crystal of corresponding 16-deacetoxy-12-epi-scalarafuran.
Journal title
Tetrahedron
Serial Year
2011
Journal title
Tetrahedron
Record number
1103624
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