Author/Authors :
Ji-Yeon Kim، نويسنده , , Yu Mu، نويسنده , , Xiangdan Jin، نويسنده , , Seok-Hwi Park، نويسنده , , Van-Thoai Pham، نويسنده , , Dong Keun Song، نويسنده , , Kee-Young Lee، نويسنده , , Won-Hun Ham، نويسنده ,
Abstract :
The concise, stereocontrolled syntheses of DAB-1 and d-fagomine were achieved utilizing chiral oxazine. The key features in these strategies are the stereoselective intramolecular oxazine formation catalyzed by palladium(0), and pyrrolidine and piperidine formation by catalytic hydrogenation of oxazine.
Keywords :
Natural product , Catalytic hydrogenation , d-Fagomine , Pd(0) catalyst , oxazine , DAB-1
