Title of article
Synthesis of 4-aza tricyclo [6.2.2.01,6]dodecenone and photoreactions: a stereoselective, entry to aza-polycyclic systems related to magellanine and congeners
Author/Authors
Vishwakarma Singh، نويسنده , , Pravin Bhalerao، نويسنده , , Shaikh M. Mobin، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
6
From page
238
To page
243
Abstract
A stereoselective, route to aza-polycyclic systems related to magellanine, and congeners from simple aromatic precursor is described. Oxidative dearomatization leading to a highly reactive spiroepoxycyclohexa-2,4-dienone, intramolecular inverse demand π4s+π2s cycloaddition and photochemical reactions are key features of our approach.
Keywords
intramolecular cycloaddition , 4-dienone , Diels–Alder reaction , Spiroepoxycyclohexa-2 , Tandem reaction , Oxidative dearomatization
Journal title
Tetrahedron
Serial Year
2012
Journal title
Tetrahedron
Record number
1104036
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