• Title of article

    Synthesis of (−)-benzolactam-V8 by application of asymmetric aziridination

  • Author/Authors

    Itsara Khantikaew، نويسنده , , Masato Takahashi، نويسنده , , Takuya Kumamoto، نويسنده , , Noriyuki Suzuki، نويسنده , , Tsutomu Ishikawa، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2012
  • Pages
    5
  • From page
    878
  • To page
    882
  • Abstract
    (−)-Benzolactam-V8, an artificially-designed cyclic dipeptide with strong tumor-promoter activity, was synthesized from benzyl (S)-N-(2-formylphenyl)-N-methylvalinate by application of guanidinium ylide-participated asymmetric aziridination followed by the reductive ring-opening reaction of 3-arylaziridine-2-carboxylate formed.
  • Keywords
    3-Arylaziridine-2-carboxylate , ring-opening reaction , (?)-Benzolactam-V8 , Asymmetric synthesis , Guanidinium ylide
  • Journal title
    Tetrahedron
  • Serial Year
    2012
  • Journal title
    Tetrahedron
  • Record number

    1104115