Author/Authors :
Attfield، J. Paul نويسنده , , Ley، Steven V. نويسنده , , Smith، Martin D. نويسنده , , Lohmann، Sophie نويسنده , , Andrews، Stephen P. نويسنده , , Burke، Brenda J. نويسنده , , Tanaka، Hirohisa نويسنده , , Kaneko، Kimiyoshi نويسنده ,
Abstract :
The utility of perovskite-based materials in organic synthesis is explored through examination of a series of copper- and palladium-containing perovskites in Ullmann and Sonogashira type reactions. La0.9Ce0.1Co0.6Cu0.4O3 is identified as an effective catalyst for the synthesis of a range of biaryl ether and thioether functionalities, whilst a Cu- and Pdcontaining perovskite is effective in the Sonogashira reaction. These results suggest that perovskites may be useful leads in the search for new catalysts and reagents for organic synthesis.
Keywords :
cross-coupling , Perovskite , Catalyst , Ullmann , Sonogashira
