Title of article
Enantiospecific first total synthesis of (6S,7R)-silphiperfolan-6-ol
Author/Authors
A. Srikrishna، نويسنده , , Gopalasetty Nagaraju، نويسنده , , Vishal M. Sheth، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
7
From page
2650
To page
2656
Abstract
Enantiospecific first total synthesis of the angular triquinane sesquiterpene (6S,7R)-silphiperfolan-6-ol has been accomplished, starting from 2-(3-isopropenyl-2-methylene-1-methylcyclopent-1-yl)acetic acid (readily available from (R)-limonene) employing an efficient, regioselective intramolecular rhodium carbenoid insertion into the CH bond of a tertiary methyl group as the key step.
Keywords
Limonene , Silphiperfolane , Enantiospecific synthesis , Angular triquinanes , Rhodium carbenoid CH insertion
Journal title
Tetrahedron
Serial Year
2012
Journal title
Tetrahedron
Record number
1104318
Link To Document