Title of article
CuCl-catalyzed stereoselective conjugate addition of Grignard reagents to 2,3-allenoates
Author/Authors
Jian He، نويسنده , , Zhan Lu، نويسنده , , Guobi Chai، نويسنده , , Chunling Fu، نويسنده , , Shengming Ma، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
6
From page
2719
To page
2724
Abstract
CuCl was found to be an efficient catalyst for the conjugate addition of 2,3-allenoates with Grignard reagents to synthesize poly-substituted β,γ-unsaturated alkenoates with high stereoselectivity in good to excellent yields. Primary, secondary, and tertiary alkyl, vinyl or phenyl Grignard reagents may all be used.
Keywords
2 , Grignard reagents , Copper-catalysis , Conjugate addition , 3-Allenoates
Journal title
Tetrahedron
Serial Year
2012
Journal title
Tetrahedron
Record number
1104327
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