Title of article
Enantiospecific total synthesis of 15-hydroxy-5-(methoxymethoxy)crinipellin-9-one
Author/Authors
A. Srikrishna، نويسنده , , V. Gowri، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
10
From page
3046
To page
3055
Abstract
Enantiospecific total synthesis of the crinipellin mentioned in the title was accomplished. In the present synthesis cyclopentane ring in campholenaldehyde was identified as the B-ring, two intramolecular rhodium carbenoid CH insertion reactions were employed for the construction of the A and C rings, and an intramolecular Michael addition reaction was utilized for the construction of the D-ring of crinipellin.
Keywords
Intramolecular rhodium carbenoid CH insertion , Crinipellins , Campholenaldehyde , Enantiospecific synthesis , Intramolecular Michael addition , Tetraquinanes
Journal title
Tetrahedron
Serial Year
2012
Journal title
Tetrahedron
Record number
1104362
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