Title of article
A N-heterocyclic carbene (NHC) platinum complex as pre-catalyst for the intramolecular hydroamination of olefins with secondary alkylamines and oxidative amination of ω-alkenic amines
Author/Authors
Rui Zhang، نويسنده , , Qin Xu، نويسنده , , Liang-yong Mei، نويسنده , , Sheng-ke Li، نويسنده , , Min Shi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
7
From page
3172
To page
3178
Abstract
A N-heterocyclic carbene (NHC) platinum complex 3 prepared from BINAM was found to be a highly effective pre-catalyst for the intramolecular hydroamination of olefins with secondary alkylamines to give the corresponding intramolecular hydroamination products in excellent yields. The substrate scope has been carefully examined and the plausible reaction mechanism has been also proposed.
Keywords
Intramolecular hydroamination , Platinum complex , N-heterocyclic carbene
Journal title
Tetrahedron
Serial Year
2012
Journal title
Tetrahedron
Record number
1104379
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