Title of article
Unexpected cis-Selectivity in (Sylvestre) Julia Olefinations with Bu3Sn-Containing Allyl Benzothiazolyl Sulfones: Stereoselective Synthesis of 1,3-Butadienyl- and 1,3,5-Hexatrienylstannanes
Author/Authors
Bruckner، Reinhard نويسنده , , Sorg، Achim نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-288
From page
289
To page
0
Abstract
Bu3Sn-substituted benzothiazolyl sulfones 1c, 1d, and 1f were subjected to Julia olefination reactions with a variety of aldehydes. cis-Selectivities up to 97:3 were obtained by using KHMDS as base in THF.
Keywords
alkenylstannanes , dienes , Julia-Lythgoe olefination , Stereoselectivity , trienes
Journal title
Synlett
Serial Year
2005
Journal title
Synlett
Record number
110444
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