Title of article
First enantioselective total synthesis of (S)-(−)-longianone
Author/Authors
Ramu Sridhar Perali، نويسنده , , Seshadri Kalapati، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
4
From page
3725
To page
3728
Abstract
An efficient stereoselective synthesis of (S)-(−)-longianone was achieved from sugar derived 1,2-cyclopropanecarboxylate involving bromonium ion mediated solvolytic ring opening and a one-pot dehydrohalogenation, stereoselective intramolecular hetero Michael addition (IHMA) and ester hydrolysis as key steps.
Keywords
1 , 4]nonane , Carbohydrates , One-pot reaction , 1 , Intramolecular hetero Michael addition , 2-Cyclopropanecarboxylate
Journal title
Tetrahedron
Serial Year
2012
Journal title
Tetrahedron
Record number
1104446
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