Title of article :
Radical Deoxygenation of 3-Azatricyclo[2.2.1.02,6]heptan-5-ols to 1,2-Dihydropyridines
Author/Authors :
Hodgson، David M. نويسنده , , Jones، Matthew L. نويسنده , , Maxwell، Christopher R. نويسنده , , Ichihara، Osamu نويسنده , , Matthews، Ian R. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
Radical deoxygenations of 7-alkyl-1-tosyl-3-azatricyclo[2.2.1.02,6]heptan-5-ols 9 (R = alkyl) give 7-alkyl-4-tosyl-2-azabicyclo [2.2.1]hept-5-enes 10, whereas 7-aryl-1-tosyl-3-azatricyclo[2.2.1.02,6]heptan-5-ols 9 (R = aryl) give 2-aryl-5-tosyl-1,2dihydropyridines 12.
Keywords :
Dihydropyridines , Alcohols , Free radicals , Deoxygenation , Rearrangements
