Author/Authors :
Tomoko Yajima، نويسنده , , Ishrat Jahan، نويسنده , , Takayuki Tonoi، نويسنده , , Manami Shinmen، نويسنده , , Aya Nishikawa، نويسنده , , Kanako Yamaguchi، نويسنده , , Izumi Sekine، نويسنده , , Hajime Nagano، نويسنده ,
Abstract :
Photoinduced radical perfluoroalkylation of various simple electron-deficient olefins was achieved in the presence of an aqueous Na2S2O3 solution. The reactions proceeded smoothly to give addition or addition–elimination products. The ability of the products to be used as radical precursors or Michael acceptors was also demonstrated.
Keywords :
Iodoperfluoroalkylation , Electron-deficient olefin , Photoinduced radical reaction , addition–elimination reaction
