• Title of article

    Enantiodivergent synthesis of (+)- and (−)-isolaurepan

  • Author/Authors

    Gonzalo Pazos، نويسنده , , Manuel Pérez، نويسنده , , Zoila G?ndara، نويسنده , , Generosa G?mez، نويسنده , , Yagamare Fall، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2012
  • Pages
    10
  • From page
    8994
  • To page
    9003
  • Abstract
    The enantiodivergent synthesis of (+)-and (−)-isolaurepan was achieved from a common chiral template easily available from tri-O-acetyl-d-glucal, using as key step a diastereoselective thermal Claisen rearrangement, combined with a ring expansion reaction using trimethylsilyldiazomethane.
  • Keywords
    Marine toxins , Claisen rearrangement , 2 , 6-syn-Disubstituted tetrahydropyrans , Enantioselective synthesis
  • Journal title
    Tetrahedron
  • Serial Year
    2012
  • Journal title
    Tetrahedron
  • Record number

    1105070