Title of article
Tishchenko Reaction Using an Iridium-Ligand Bifunctional Catalyst
Author/Authors
Suzuki، Takeyuki نويسنده , , Yamada، Taichiro نويسنده , , Matsuo، Tomohito نويسنده , , Watanabe، Kazuhiro نويسنده , , Katoh، Tadashi نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-144
From page
145
To page
0
Abstract
Tishchenko reaction of aldehydes in the presence of an amino alcohol-based Ir bifunctional catalyst was developed. The reaction proceeds with 1 mol% of the catalyst and 20-30 mol% of K2CO3 in acetonitrile at room temperature to give the corresponding dimeric esters in good yield.
Keywords
Aldehydes , esters , hydrogen transfer , iridium catalyst , Tishchenko reaction
Journal title
Synlett
Serial Year
2005
Journal title
Synlett
Record number
110508
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