• Title of article

    A simple and efficient reusable polystyrene-supported palladium catalyst for Hiyama cross-coupling

  • Author/Authors

    Carine Diebold، نويسنده , , Antoine Derible، نويسنده , , Jean-Michel Becht، نويسنده , , Claude Le Drian، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2013
  • Pages
    4
  • From page
    264
  • To page
    267
  • Abstract
    An efficient synthesis of biaryls using a Hiyama reaction between aryl iodides and aryltrialkoxysilanes in the presence of a diphenylphosphinomethylpolystyrene-supported palladium catalyst is described. The cross-coupling proceeds in the presence of only 0.1 mol % of supported palladium. The catalyst can be used at least four times and the palladium leaching is extremely low (ca. 1% of the initial amount).
  • Keywords
    biaryls , Heterogeneous catalysis , Polymers , Green chemistry
  • Journal title
    Tetrahedron
  • Serial Year
    2013
  • Journal title
    Tetrahedron
  • Record number

    1105303