Title of article :
A First Example Using o-Iodoxybenzoic Acid (IBX) in Combination with Tetraethylammonium Bromide (TEAB) for Ring Expansion of 1,3-Dithiolanes and 1,3-Dithianes
Author/Authors :
Shukia، Vidyanand G. نويسنده , , Salgaonkar، Paresh D. نويسنده , , Akamanchi، Krishnacharya G. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
A novel one-pot procedure for the synthesis of dihydro1,4-dithiins and dihydro-l,4-dithiepines from the corresponding 1,3-dithiolanes and 1,3-dithianes using o-iodoxybenzoic acid (IBX) in combination with tetraethylammonium bromide (TEAB) is described. The salient features of the protocol include mild reaction conditions, short reaction times and high yields.
Keywords :
tetraethylammonium bromide (TEAB) , o-iodoxybenzoic acid (IBX) , dithiepines , dithiins