Title of article
Seleno-Imine: A New Class of Versatile, Modular N,Se Ligands for Asymmetric Palladium-Catalyzed Allylic Alkylation
Author/Authors
Braga، Antonio L. نويسنده , , Paix?o، M?rcio W. نويسنده , , Marin، Graciane نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-1674
From page
1675
To page
0
Abstract
The palladium-catalyzed asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate with dimethyl malonate in the presence of chiral seleno-imine ligands derived from an inexpensive and easily available chiral pool was investigated. Excellent yield and enantioselectivity (up to 97% ee) was achieved when ligand 4a was used.
Keywords
allylic alkylations , seleno-imines , Palladium-catalyzed
Journal title
Synlett
Serial Year
2005
Journal title
Synlett
Record number
110556
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