Author/Authors :
Minoru Ozeki، نويسنده , , Megumi Satake، نويسنده , , Toshinori Toizume، نويسنده , , Shintaro Fukutome، نويسنده , , Kenji Arimitsu، نويسنده , , Shinzo Hosoi، نويسنده , , Tetsuya Kajimoto، نويسنده , , Hiroki Iwasaki، نويسنده , , Naoto Kojima، نويسنده , , Manabu Node، نويسنده , , Masayuki Yamashita، نويسنده ,
Abstract :
The first asymmetric total synthesis of (+)-taiwaniaquinol D and (−)-taiwaniaquinone D isolated from Taiwania cryptomerioides was attained by using the intramolecular asymmetric Heck reaction. The reaction provided a tricyclic intermediate that would be available for the asymmetric total synthesis of various abeo-abietane-type diterpenoids.
Keywords :
(+)-Taiwaniaquinol D , Diterpenoid , abeo-Abietane , (?)-Taiwaniaquinol B , Intramolecular asymmetric Heck reaction , (?)-Taiwaniaquinone D
