Title of article
Neutral guest capture by a cationic water-soluble pillar[5]arene in water
Author/Authors
Yingjie Ma، نويسنده , , Jun Min Xue، نويسنده , , Zibin Zhang، نويسنده , , Xiaodong Chi، نويسنده , , Feihe Huang، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
4
From page
4532
To page
4535
Abstract
A cationic water-soluble pillar[5]arene offering a well-defined cavity with hydrophobic inner surface can capture neutral guests, even water-insoluble guests, into its cavity via hydrophobic forces. The binding ability depends upon guest hydrophobicity. The higher guest hydrophobicity contributes to the higher host affinity. Methanol and ethanol do not show any affinity for the host at all, because they are too hydrophilic for the host to compete with water.
Keywords
Tri-O-acetyl-d-glucal , Type I Ferrier Rearrangement , TiCl3(OTf) , 2 , 3 , 4 , 6-Tri-O-acetyl-d-glucal , 3-Unsaturated-O-glycoside
Journal title
Tetrahedron
Serial Year
2013
Journal title
Tetrahedron
Record number
1105817
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