Title of article
Sub-stoichiometric oxidation of benzylic alcohols with commercially available activated MnO2 under oxygen atmosphere: a green modification of the benzylic oxidation
Author/Authors
Akio Kamimura، نويسنده , , Hiroyuki Komatsu، نويسنده , , Takaaki Moriyama، نويسنده , , Yuichiro Nozaki، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
5
From page
5968
To page
5972
Abstract
Benzylic and allylic alcohols were readily converted into aldehydes and ketones in the presence of sub-stoichiometric amounts of activated MnO2 under oxygen atmosphere. No over-oxidation to carboxylic acid happened. The present procedure dramatically reduces the amounts of MnO2 necessary for the oxidation and provides a greener modification of widely used oxidation method.
Keywords
Green oxidation , Benzylic oxidation , aerobic oxidation , Manganese oxide
Journal title
Tetrahedron
Serial Year
2013
Journal title
Tetrahedron
Record number
1105989
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