Title of article
A total synthesis of the epoxyquinone natural product cytosporin D
Author/Authors
Jagadeshwar Vannada، نويسنده , , Lennart Niehues، نويسنده , , Burkhard K?nig، نويسنده , , Goverdhan Mehta، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
7
From page
6034
To page
6040
Abstract
A synthesis of epoxyquinone natural product cytosporin D from the readily available Diels–Alder adduct of cyclopentadiene and 2-prenyl-p-benzoquinone, has been accomplished. This approach leverages the stereochemical predisposition of the norbornyl-fused systems towards convex face reactivity as an enabler for the stereoselective construction of the pyran ring.
Keywords
Epoxyquinone natural products , Stereoselective reduction , Wittig olefination , Diels–Alder reaction , Oxycylization
Journal title
Tetrahedron
Serial Year
2013
Journal title
Tetrahedron
Record number
1105995
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