Title of article
Formation of homoallylic bromohydrins in indium-mediated allylation reactions of phenacyl bromides in aqueous solution
Author/Authors
Mei-Huey Lin، نويسنده , , Chung-Kai Kuo، نويسنده , , Wei-Cheng Lin، نويسنده , , Yen-Chih Huang، نويسنده , , Yu-Ting Tsai، نويسنده , , Kung-Yu Liang، نويسنده , , Yi-Syuan Li، نويسنده , , Tsung-Hsun Chuang، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
6
From page
8263
To page
8268
Abstract
A method is described for carrying out indium-mediated allylation reactions of phenacyl bromides in aqueous solution that form homoallylic bromohydrins. By employing subsequent base treatment, the homoallylic bromohydrins were converted to allylic epoxides. Finally, the process has been used as a key step in a concise sequence for the synthesis of 3-allylbenzofuran.
Keywords
Allylation , Indium , Homoallylic bromohydrins , Phenacyl bromides , Epoxides
Journal title
Tetrahedron
Serial Year
2013
Journal title
Tetrahedron
Record number
1106257
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