Title of article
Iron-Catalyzed Chemoselective Cross-Coupling of Primary and Secondary Alkyl Halides with Arylzinc Reagents
Author/Authors
Nakamura، Eiichi نويسنده , , Nakamura، Masaharu نويسنده , , Ito، Shingo نويسنده , , Matsuo، Keiko نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-1793
From page
1794
To page
0
Abstract
Functional-group-compatible cross-coupling reaction of alkyl halides with arylzinc reagents takes place under iron catalysis in the presence of TMEDA, producing a variety of aromatic compounds in good to excellent yield. The pronounced effect of a magnesium salt was found to be the key to the promotion of the iron-catalyzed coupling reaction.
Keywords
cross-coupling , alkyl halides , substitution , zinc reagents , iron catalyst
Journal title
Synlett
Serial Year
2005
Journal title
Synlett
Record number
110630
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