Title of article
Nickel-Catalyzed Electrophilic Amination of Organozinc Halides
Author/Authors
Berman، Ashley M. نويسنده , , Johnson، Jeffrey S. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-1798
From page
1799
To page
0
Abstract
The nickel-catalyzed electrophilic amination of organozinc halides with O-benzoyl N,N-dialkyl hydroxylamines allows for the preparation of a variety of aryl and alkyl tertiary amines in good yield. The reaction is noteworthy for the mild reaction conditions employed (room temperature) and the ease of product purification (acid/base extractive work up).
Keywords
amination , organometallic reagents , nickel , umpolung , catalysis
Journal title
Synlett
Serial Year
2005
Journal title
Synlett
Record number
110632
Link To Document