Title of article :
Nickel-Catalyzed Electrophilic Amination of Organozinc Halides
Author/Authors :
Berman، Ashley M. نويسنده , , Johnson، Jeffrey S. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
The nickel-catalyzed electrophilic amination of organozinc halides with O-benzoyl N,N-dialkyl hydroxylamines allows for the preparation of a variety of aryl and alkyl tertiary amines in good yield. The reaction is noteworthy for the mild reaction conditions employed (room temperature) and the ease of product purification (acid/base extractive work up).
Keywords :
amination , organometallic reagents , nickel , umpolung , catalysis
