Title of article
Dramatic Effect of Boron-Based Lewis Acids in Cross-Metathesis Reactions
Author/Authors
Grimaud، Laurence نويسنده , , Vedrenne، Emeline نويسنده , , Dupont، Herve نويسنده , , Oualef، Sabrina نويسنده , , Elkaïm، Laurent نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-66
From page
67
To page
0
Abstract
Amino compounds such as allylic carbamates or amides are poor partners in cross-metathesis reactions because of possible coordination of the emerging carbene to the polar functional group. Whereas the use of titanium Lewis acid catalysts was unsatisfactory, an impressive increase in yields was obtained with boron-based Lewis acids.
Keywords
cross-metathesis , amino compounds , boron , Ruthenium , Lewis acid
Journal title
Synlett
Serial Year
2005
Journal title
Synlett
Record number
110651
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