Title of article
Quaternary ammoniums and a cationic sodium complex as supramolecular catalysts in ring-opening of epoxides by amines
Author/Authors
Coralie Thomas، نويسنده , , Sébastien Brut، نويسنده , , Brigitte Bibal، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
5
From page
1646
To page
1650
Abstract
Supramolecular ionic organocatalysts and a metal-based catalyst were investigated in the ring-opening of epoxides by amines, without any artifice to enhance conversion (i.e., solvophobic effect, extended reaction time, heating, excess of amine, high catalyst loading). Different β-amino-alcohols were obtained in satisfying conversion (50–80%) in 24 h, under mild conditions.
Keywords
organocatalysis , Ring-opening , Hydrogen bond , epoxide , Ionic catalyst
Journal title
Tetrahedron
Serial Year
2014
Journal title
Tetrahedron
Record number
1106803
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