Title of article
An Unexpected Double-Bond Isomerization Catalyzed by Crabtree’s Iridium(I) Catalyst
Author/Authors
Krel، Michael نويسنده , , Lallemand، Jean-Yves نويسنده , , Guillou، Catherine نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-2042
From page
2043
To page
0
Abstract
The first iridium-catalyzed isomerization of an exocyclic into an endocyclic double bond is described. A mechanism is proposed for this reaction. Crabtree’s catalyst thus allows the migration of a double bond that does not occur under classical conditions.
Keywords
catalysis , Isomerization , aldol-like reaction , olefination , iridium
Journal title
Synlett
Serial Year
2005
Journal title
Synlett
Record number
110728
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