Title of article :
An Unexpected Double-Bond Isomerization Catalyzed by Crabtree’s Iridium(I) Catalyst
Author/Authors :
Krel، Michael نويسنده , , Lallemand، Jean-Yves نويسنده , , Guillou، Catherine نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
The first iridium-catalyzed isomerization of an exocyclic into an endocyclic double bond is described. A mechanism is proposed for this reaction. Crabtree’s catalyst thus allows the migration of a double bond that does not occur under classical conditions.
Keywords :
catalysis , Isomerization , aldol-like reaction , olefination , iridium
