Title of article :
Iridium-Catalyzed Carbonyl Allylations by Allylic Alcohols with Tin(II) Chloride oshiya Chiyo
Author/Authors :
Masuyama، Yoshiro نويسنده , , Kurusu، Yasuhiko نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
Iridium complex [IrCl(cod)]2 can function as a catalyst for the allylation of aldehydes and ketones by allylic alcohols upon addition of an equimolar amount of SnCl2 in THF-H2O; the reaction is carried out between room temperature and 50 °C to give the corresponding homoallylic alcohols.
Keywords :
nucleophilic addition , carbonyl allylation , (pi)-allyliridium , tin(II) chloride , allylic alcohols
