• Title of article

    Enantioselective Aza-Diels-Alder Reaction Catalyzed by a Chiral Br?nsted Acid: Effect of the Additive on the Enantioselectivity

  • Author/Authors

    Tamura، Yukio نويسنده , , Akiyama، Takahiko نويسنده , , Fuchibe، Kohei نويسنده , , Itoh، Junji نويسنده , , Morita، Hisashi نويسنده ,

  • Pages
    -140
  • From page
    141
  • To page
    0
  • Abstract
    Danishefsky’s diene and aldimine underwent aza Diels-Alder reaction under the influence of chiral phosphoric acid derived from (R)-BINOL as a chiral Br?nsted acid to afford piperidinone derivatives in good to high enantioselectivity. Addition of CH3CO2H improved both reactivity and enantioselectivity.
  • Keywords
    Danishefsky’s diene , asymmetric synthesis , chiral Br?nsted acid , aza-Diels-Alder reaction
  • Journal title
    Astroparticle Physics
  • Record number

    110923

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=110923