Title of article
Development of a Hemilabile P-P=O Ligand Based on the Concept of Conformational Control
Author/Authors
Kondo، Kazuhiro نويسنده , , Suzuki، Kiyoto نويسنده , , Ishii، Satoru نويسنده , , Aoyama، Toyohiko نويسنده ,
Pages
-647
From page
648
To page
0
Abstract
Development of a new hemilabile P-P=O ligand based on the concept of conformational control is described. In Rh-catalyzed enantioselective phenylation of aromatic aldehydes with phenylboronic acid, MOD-DIOP monophosphine oxide is shown to function as a good ligand.
Keywords
Boronic acid , hemilabile chiral ligands , asymmetric arylation , optically active diarylmethanol , rhodium catalysts
Journal title
Astroparticle Physics
Record number
111039
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