• Title of article

    Manganese-Promoted (beta)-Elimination Reactions: Totally Stereoselective Synthesis of (E)-(alpha),(beta)-Unsaturated Esters

  • Author/Authors

    Amo، Vicente del نويسنده , , Concellon، Jose M. نويسنده , , Rodriguez-Solla، Humberto نويسنده ,

  • Pages
    -314
  • From page
    315
  • To page
    0
  • Abstract
    Stereoselective (beta)-elimination of 2-bromo-3-hydroxy­esters is achieved by using non-preactivated manganese and tri­ methylsilyl chloride, to yield (E)-(alpha),(beta)-unsaturated esters with total diastereoselectivity.
  • Keywords
    eliminations , manganese , alkenes , diastereoselectivity , esters
  • Journal title
    Astroparticle Physics
  • Record number

    111046