Title of article
Manganese-Promoted (beta)-Elimination Reactions: Totally Stereoselective Synthesis of (E)-(alpha),(beta)-Unsaturated Esters
Author/Authors
Amo، Vicente del نويسنده , , Concellon، Jose M. نويسنده , , Rodriguez-Solla، Humberto نويسنده ,
Pages
-314
From page
315
To page
0
Abstract
Stereoselective (beta)-elimination of 2-bromo-3-hydroxyesters is achieved by using non-preactivated manganese and tri methylsilyl chloride, to yield (E)-(alpha),(beta)-unsaturated esters with total diastereoselectivity.
Keywords
eliminations , manganese , alkenes , diastereoselectivity , esters
Journal title
Astroparticle Physics
Record number
111046
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