• Title of article

    Ligand Tailoring: The First Modular Assembly of Atropisomeric Biarylbisphosphine Ligands

  • Author/Authors

    Leroux، Frederic نويسنده , , Mettler، Hanspeter نويسنده ,

  • Pages
    -765
  • From page
    766
  • To page
    0
  • Abstract
    Strategies based on highly selective halogen-metal permutations have been devised and applied enabling the modular assembly of atropisomeric biaryl bisphosphines. After resolution on chiral column, the ligands were tested in benchmark hydrogenation reactions affording good to excellent enantioselectivity.
  • Keywords
    Phosphorus , catalysts , bi­aryls , hydrogenation , lithiation
  • Journal title
    Astroparticle Physics
  • Record number

    111087