Title of article
Ligand Tailoring: The First Modular Assembly of Atropisomeric Biarylbisphosphine Ligands
Author/Authors
Leroux، Frederic نويسنده , , Mettler، Hanspeter نويسنده ,
Pages
-765
From page
766
To page
0
Abstract
Strategies based on highly selective halogen-metal permutations have been devised and applied enabling the modular assembly of atropisomeric biaryl bisphosphines. After resolution on chiral column, the ligands were tested in benchmark hydrogenation reactions affording good to excellent enantioselectivity.
Keywords
Phosphorus , catalysts , biaryls , hydrogenation , lithiation
Journal title
Astroparticle Physics
Record number
111087
Link To Document