Title of article :
Rh(I)-Catalyzed O-Silylation of Alcohol with Vinylsilane
Author/Authors :
Jun، Chul-Ho نويسنده , , Park، Jung-Woo نويسنده , , Chang، Hoon-Jo نويسنده ,
Abstract :
Silyl ethers can be produced from alcohols and vinylsilanes under a rhodium(I) catalyst. The reaction is believed to proceed through an O-H bond cleavage of alcohol by rhodium(I) complex and a subsequent hydride insertion into vinylsilane followed by (beta)-silyl elimination of the resulting (beta)-silylethyl rhodium(III) complex.
Keywords :
silyl ether , alcohol , vinylsilane , O-H bond cleavage , Wilkinson’s complex
Journal title :
Astroparticle Physics
