Title of article :
The Hiratani-Double-Claisen Rearrangement as a Key Step in the Preparation of Sequential Bis(8-hydroxyquinoline) Ligands
Author/Authors :
Frohlich، Roland نويسنده , , Albrecht، Markus نويسنده , , Osetska، Olga نويسنده ,
Abstract :
Symmetric and sequential isobutenylidene-bridged bis-(8-hydroxyquinoline)s are prepared by application of the Hiratani-double-Claisen rearrangement as a key step in the reaction sequence. The formation of a dinuclear helicate-type zinc(II) complex is also described.
Keywords :
Self-assembly , Complexes , supramolecular chemistry , Claisen rearrangement , 8-hydroxyquinoline
Journal title :
Astroparticle Physics