• Title of article

    Metallation versus Heteroatom Lithium Complexation: Mono- and ­Dilithiation of Dipyridylpiperazines

  • Author/Authors

    Louerat، Frederic نويسنده , , Gros، Philippe C. نويسنده , , Fort، Yves نويسنده ,

  • Pages
    -1378
  • From page
    1379
  • To page
    0
  • Abstract
    BuLi-LiDMAE induced the efficient lithiation of di­pyridylpiperazines despite strong competing lithium coordination by several nitrogen atoms. Symmetrical substrates led to a one-pot dilithiation while dissymmetrical species gave mono- or dilithiation under temperature control.
  • Keywords
    Heterocycles , pyridine , regioselectivity , Aggregation , Lithiation
  • Journal title
    Astroparticle Physics
  • Record number

    111153