Title of article
Ag(I)-Catalyzed Michael Additions of (beta)-Ketoesters to Nitroalkenes in Water: Remarkable Effect of Water as a Reaction Medium on Reaction Rates
Author/Authors
Kobayashi، Shu نويسنده , , Shirakawa، Seiji نويسنده ,
Pages
-140
From page
141
To page
0
Abstract
AgOTf-PPh3 complex-catalyzed Michael additions of (beta)-ketoesters to nitroalkenes in water were performed. The system promotes the reaction efficiently only in water, and interestingly the reaction does not proceed well in organic solvents. In addition, this reaction system could be applied to catalytic asymmetric synthesis in water.
Keywords
Michael additions , Silver , asymmetric synthesis , Solvent effects , water
Journal title
Astroparticle Physics
Record number
111160
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