• Title of article

    Efficient Synthesis of (E)-3-Alkylidene-2(3H)-furanones from 3-(1-Hydroxy­alkyl)-2-silyloxyfurans

  • Author/Authors

    Boukouvalas، John نويسنده , , Marion، Olivier نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2006
  • Pages
    -1510
  • From page
    1511
  • To page
    0
  • Abstract
    Several unsubstituted (E)-3-alkylmethylidene- and (E)-3-(arylmethylidene)-2(3H)-furanones have been synthesized in highly stereoselective fashion by mesylation-elimination of 3-(1-hydoxyalkyl)-2-silyloxyfurans. The latter were prepared from 2triisopropylsilyloxy-3-bromofuran by halogen-lithium exchange and reaction of the in situ generated 3-lithiated silyloxyfuran with aldehydes.
  • Keywords
    2-silyloxyfurans , bromination , Lithiation , lactones , Stereoselectivity
  • Journal title
    Synlett
  • Serial Year
    2006
  • Journal title
    Synlett
  • Record number

    111181

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=111181