Title of article :
Preparation of Polystyrene-Supported (alpha)-Seleno Acetate and Application to Solid-Phase Synthesis of (beta)-Keto Esters
Author/Authors :
Huang، Xian نويسنده , , Qian، Hao نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2006
Abstract :
A novel polystyrene-supported (alpha)-seleno acetate has been developed. This novel resin was treated with LDA to produce a se:selenium-stabilized carbanion, which reacted with aldehydes, followed by selenoxide syn-elimination to give (beta)-keto esters.
Keywords :
selenoxide syn-elimination , (alpha)-seleno acetate , polymer reagent , solid-phase synthesis , (beta)-keto esters