Author/Authors :
Kantam، M. Lakshmi نويسنده , , Toru، Takeshi نويسنده , , Giribabu، L. نويسنده , , Chandrasekharam، M. نويسنده , , Mohan، S. Madan نويسنده , , Rao، Ch. Srinivasa نويسنده , , Reddy، M. Ramesh نويسنده , , Reddy، P. Yella نويسنده ,
Abstract :
A novel single-step preparation of free-base and metalloporphyrazines from maleonitriles was accomplished for the first time by treatment with metal salts, hexamethyldisilazane (HMDS) and p-toluene sulfonic acid (PTSA) in DMF at 120 °C. This reaction provides a new preparative method under mild conditions for direct synthesis of metalloporphyrazines having a variety of metals and substituted maleonitriles.
Keywords :
Macrocycles , Porphyrazines , maleonitrile , template , hexamethyldisilazane
