• Title of article

    Remarkable Effects of Additives to Facilitate Aza-Mannich Type Reaction: A Rapid Access to (beta)-Amino Ketone O-Alkyl Oximes

  • Author/Authors

    Hachiya، Iwao نويسنده , , Shimizu، Makoto نويسنده , , Tanaka، Mitsue نويسنده , , Itoh، Tomohiro نويسنده ,

  • Pages
    -1686
  • From page
    1687
  • To page
    0
  • Abstract
    Aza-Mannich-type reaction proceeded between imines and the aza-enolates formed from (alpha)-iodomethyl ketone O-alkyl oximes with titanium tetraiodide to give (beta)-amino ketone O-alkyl oximes in good to excellent yields. Remarkable effects of added ­silica gel or molecular sieves (4 (angstrom)) were observed to promote the addition reactions.
  • Keywords
    aza-Mannich-type reaction , titanium tetraiodide , iodo­acetone O-benzyl oxime , (beta)-amino ketone O-alkyl oximes
  • Journal title
    Astroparticle Physics
  • Record number

    111220