Author/Authors :
Yoshida، Takashi نويسنده , , Hattori، Kazuyuki نويسنده , , Okimoto، Mitsuhiro نويسنده , , Numata، Kaori نويسنده , , Hoshi، Masayuki نويسنده , , Tomozawa، Kenta نويسنده , , Komata، Masashi نويسنده ,
Abstract :
Dimethyl aminomalonates were electrochemically oxidized in methanol to afford the corresponding cyclization products through the formation of carbon-carbon bonds. Optimum yields were obtained when NaCN was utilized as the supporting electrolyte at room temperature. Presumably, the electrooxidation involves a twoelectron oxidation process.
Keywords :
dimethyl ester , cyclizations , electrochemical oxidations , Heterocycles , Electron transfer