Infra-red and Raman spectroscopic study on the thermal stability and high temperature transformation of hydroazafullerene C59HN Original Research Article

Hydroazafullerene C59HN was studied by vibrational infra-red and Raman spectroscopy and its thermal stability was examined. Fingerprints modes were identified and unambiguously differentiate it from bisazafullerene. At 700 K full transformation to bisazafullerene occurred, while an intermediate metastable phase was identified at 540 K showing different spectra where the splitting of most of the lines is strongly reduced.