Title of article
A novel efficient synthesis and characterization of crystalline chromium-silicate molecular sieves with MFI structure Original Research Article
Author/Authors
T. Selvam، نويسنده , , M.P. Vinod، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1996
Pages
5
From page
197
To page
201
Abstract
Chromium has been substituted successfully in a silicalite structure for the first time in acidic medium. A combined application of cyclic voltammetry (E12 = +588 mV vs. standard calomel electrode) and electron spin resonance reveals that both Cr3+ and Cr5+ are present as part of the structure with octahedral coordination and their reversible transformation within the structure is primarily responsible for the catalytic behaviour.
Keywords
Cr-MFI molecular sieve , Molecular sieves with chromium , Cyclic voltammetry , Chromium silicalite
Journal title
Applied Catalysis A:General
Serial Year
1996
Journal title
Applied Catalysis A:General
Record number
1148267
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