Title of article
Preparation of a hybrid organic–inorganic material containing macrocyclic triolefinic 15-membered palladium(0) complex: Catalytic activity in Suzuki cross-coupling and butadiene telomerization reactions Original Research Article
Author/Authors
Belén Blanco، نويسنده , , Marina Brissart، نويسنده , , Marcial Moreno-Ma?as، نويسنده , , Roser Pleixats، نويسنده , , Ahmad Mehdi، نويسنده , , Catherine Reyé، نويسنده , , Sandrine Bouquillon، نويسنده , , Françoise Hénin، نويسنده , , Jacques Muzart، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
8
From page
117
To page
124
Abstract
The synthesis of a bis-silylated 15-membered azatriolefinic macrocycle is described as well as its co-gelification with tetraethyl orthosilicate. The resulting material was treated with Pd(dba)2 affording an hybrid organic–inorganic material containing macrocyclic palladium(0) complex covalently bonded to the silica matrix. The activity of this material as catalyst or precatalyst in Suzuki cross-coupling and telomerization of butadiene with methanol and phenol is presented.
Keywords
Cross-coupling , Macrocycles , Telomerization , Sol–gel processes , Palladium supported catalyst
Journal title
Applied Catalysis A:General
Serial Year
2006
Journal title
Applied Catalysis A:General
Record number
1152409
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